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Ironically, to pull off white you don't want most of your model to be white, only the brightest highlights. Choose a tone for your white and highlight up from there. Cool white (blue), neutral white (grey), and warm white (bleached bone/cream) are what you see most commonly, but technically you can shade up from anything (green, purple, etc.)
White is a tough color to pull off, just warning you up front.
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