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Can anyone please suggest some colors for making the textile gold trim on something like an Officio Prefectus Commisar? I'm having a hard time figuring out if its brown with buff highlight or what.

They probably used:-

Base - Retributor Armour
Shade - Reikland Fleshshade
1st Layer - Auric Armour
2nd Layer/highlight - Stormhost Silver

That's for the trim on the hat, coat and uniform (and possibly the scarf).

For the cord on the hat and the uniform I think it'd be:-

Base - Steel Legion Drab
Shade - Agrax Earthshade
Layer - Balor Brown
Highlight - Zamesi Desert

Those'd be my suggestions for those colours, they don't tend to go too tricky with paint schemes on the webstore pictures (so they wouldn't use NMM instead of just using metallics on the trim etc.). Unfortunately I can't help with non-GW colours >.<