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The ordo millitum would cover sanctioned psykers attached to the guard, but there's no named minor ordo specializing in astropaths.
There's no canon 'master' list of minor ordos and frankly I'm not sure there can be: they're more like informal committee of expertise than, say, regiments. Codes inquisition had the widest list I've seen, with stuff like the ordo astartes and ordo excorium (exterminatus weapons). Ultimately, inquisitors have infinite authority, so if they want to declare the formation of a new minor ordo, who do they answer to?
The codex inquisition list includes one minor ordo with an unknown remit consisting of a single inquisitor. I personally suspect the inquisitor in question just found a nice office somewhere and stopped going to meetings..
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