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Alright, so a Mark of Tzeentch Sorcerer takes this Relic and: "Must choose to generate at least one power from the Discipline of Tzeentch" rule vs. the Relic's "Can choose to generate powers from the Divination discipline"

Which one overwrites the other? Personally, I don't mind the Tzeentch discipline- in fact, I would probably always want to combine Divination powers with the Tzeentch ones.

Your still forced to take a Tzeentch power, if you cited the rules correctly on the new relic, it just adds a new table to chose from nothing more.

Yeah you must take at least 1 power from Tzeentch. If your Sorcerer is lvl2+ then you can take a power from Divination (or any of the other disciplines open to a Chaos Sorcerer). Also an unmarked Sorcerer could take his first power from Divination. Whilst any sorcerer still benefits from the rerolls.