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2nd one

The purple on the cloak is
Phoenecian Purple (GW)
Light dry brush Emperor's Children (GW)
Agrax Earthshade (GW) - when put over whole model
Very light dry brush Emperor's Children (GW)

The armour is:
Warplock bronze (GW)
Drybrush Balthasar Gold (GW)
Agrax Earthshade (GW) - when put over whole model
Light dry brush Auric Armour Gold (GW) from above.