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I been recently wondering who would win in a fight a Rak'Gol or a Xenomorph, i think the Rak'Gol would win sense it is like a Xenomorph but has guns.
What do you think?

I don't think they are really like the xenomorphs.. their description doesn't really match them

Xenomorphs are an infection like zombinites or ebola.
Rak'Gol are an intelligent but utter alien space faring race who are drawn to specific ancient alien artifacts and tend to murder anyone who is in the neighborhood when they pop up.

This isn't really a battle as much as it is a case of how good are the Rak'Gol sanitary procedures. We have to speculate here since we know too little about the Rak'Gol, but the 40k universe is littered with horrible viruses and the Rak'Gol are still alive so my guess is that the Rak'Gol will eventually manage to stop the infection.

By killing all the infected of course.

Well we know what molecular acid does now (alien blood) due to dark angels using it in there heavy bolters.

Poison 2+ ap d6, so alien blood is quite horrific by 40k standards at least.