A formation is not a special "squad" but a special "detachment". Models can only be a member of one detachment, so if you use Leman Russ tanks as part of a formation, they are NOT part of Combined Arms Detachment. You can take Combined Arms Detachments, Allied Detachments and formations in the same army. I'm currently building a Tyranid army that uses two formations, and a Combined Arms Detachment. Keep in mind, that the special rules for each detachment (formations included) only apply to the models IN THAT DETACHMENT. If you have a Combined Arms and a formation, the formation models DO NOT GET Objective Secured (unless the formations gives that rule to the models), but the models in the Combined Arms DO get Objective Secured. The only stipulation is that your formations and detachments all have to follow the alliance table rules.
You mentioned a formation in a Apoc expansion, so I would assume THAT one is an Apoc formation. The formation itself will identify when it can be used. Apocalypse formations are identified as such. There are formations in the Tyranid dataslates that can be used in 40K, and there is a formation in Sentinels of Terra that can only be used for Apoc.
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