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Whats a good way of painting red hair?

Base of Macharius Solar orange. Blazing orange highlighting. Yellow or red mixed with blazing orange highlights.

Simple. I use it on my Marauders.

Bestial Brown basecoat, highlight up to Blazing Orange

Terracotta with bubonic brown highlights. If you can find Terracotta....

lol, I actually have terracotta- as a well as a large assortment of browns, but no bubonic brown, or any oranges to speak of. I have blood red, and red gore to work with, as well as yellows (Iyanden Dark Sun, and golden yellow- I think I have the third yellow running around somewhere as well) that I was planning to mix up if oranges were really needed

Red hair is actually a shade of brown to blonde, orange is actually a shade of brown (go figure on both). So using straight orange, or red, wouldn't look natural, in my opinion.