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No, you would not be able to with the information that you've given. You would have to replace the slugga to get the mega armor (I dont know why it has to be a slugga, just GWs rules I guess), and while I am not 100% sure, I would guess with relative certainty that a twin linked shoota does not equal a shoota.
Edit: After looking at the codex, I would still say no you cannot as you have to have the slugga to do that, but you also have to have the slugga to exchange it for the shoota/skorcha, which in turn prevents you from getting the mega-armour. Even the other way you would not be able to do it as the armor gives you a shoota, but you need the slugga to exchange it for shoota/skorcha.
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