Actually, in this case it's rather easy to determine which weapon has the advantage.
Space Marine Sergeant
with
LC vs WS5/T5, no charge: 0.56 wounds
with
PW vs WS5/T5, no charge: 0.50 wounds
-->
LC is 12% better than
PW.
with
LC vs. WS4/T4, no charge: 0.75 wounds
with
PW vs. WS4/T4, no charge: 0.75 wounds
--> Weapons are equal.
with
LC vs WS3/T3, no charge: 1.19 wounds
with
PW vs. WS3/T3, no charge: 1.33 wounds
-->
PW is 11.8% better than
LC.
+ + +
with
LC vs WS5/T5, on the charge: 0.83 wounds
with
PW vs WS5/T5, on the charge: 0.67 wounds
-->
LC is 23.9% better than
PW.
with
LC vs WS4/T4, on the charge: 1.125 wounds
with
PW vs WS4/T4, on the charge: 1 wound
-->
LC is 12.5% better than
PW.
with
LC vs WS3/T3, on the charge: 2.07 wounds
with
PW vs WS3/T3, on the charge: 1.77 wounds
-->
LC is 16.9% better than
PW.
--------------------
Doing the same mathhamer with a Captain for comparison.
Space Marine Captain
with
LC vs WS5/T5, no charge: 1.11 wounds
with
PW vs WS5/T5, no charge: 0.89 wounds
-->
LC is 24.7% better than
PW.
with
LC vs. WS4/T4, no charge: 1.5 wounds
with
PW vs. WS4/T4, no charge: 1.33 wounds
-->
LC is 12.8% better than
PW.
with
LC vs WS3/T3, no charge: 1.77 wounds
with
PW vs. WS3/T3, no charge: 1.77 wounds
--> Weapons are equal.
+ + +
with
LC vs. WS5/T5, on the charge: 1.48 wounds
with
PW vs. WS5/T5, on the charge: 1.11 wounds
-->
LC is 33% better than
PW.
with
LC vs WS4/T4, on the charge: 2 wounds
with
PW vs WS4/T4, on the charge: 1.66 wounds
-->
LC is 20.5% better than
PW.
with
LC vs WS3/T3 on the charge: 2.37 wounds
with
PW vs WS3/T3 on the charge: 2.22 wounds
-->
LC is 6.8% better than
PW.
With higher combat skills and more attacks, the advantage lies definitely with the Lightning Claw.
Final result:
The Lighting Claw is better than the power sword in 4/6 Sgt.-Tests and 10/12 tests overall.
Both weapons are equal in 1/6 Sgt.-Tests and 2/12 tests overall.
The power sword is better than the Lightning Claw in 1/6 Sgt.-Tests and 1/12 tests overall.
In general, the Lightning Claw is better than the power sword, especially with increasing WS and number of attacks of the wielder.
The only situation where a power sword would be the better choice is if you try to play defensively against charging guardsmen or fire warriors. And how often is that gonna happen!
I hope my mathhammer is correct. I re-calculated some parts several times to be sure, but if someone finds a mistake, please point it out so this thread will become more helpful!
Postscriptum: Ninja'd!

And now you tell me that sergeants can't take a lightning claw...