I don't think you need to bake greenstuff. After it's dry, you're good to go. If you did bake it, I'd imagine it'd melt. o-o
I've heard people rub a little vegetable oil in a mold before using it, so I'd imagine there is a chance of it sticking.
GS is sticky by nature, and I can't imagine the oil would be harmful to the
GS. Just don't overload.