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Mindwar does not effect Kharn, but could it be used to target a model in the same squad as Kharn?

Yes, only Kharne is immune to Psychic powers. The unit he is with is still vulnerable.

Could we get some more info, I have the eldar codex but not which ever space marine codex Kharn is from.

More info please

Kharne is in the Chaos Space marine codex, and Has a Rule called "Blessing of the Blood God" Blessing of the Blood god grants him immunity to all psychic powers and turns force weapons directed at him into simply power weapons(not that the second part was needed since Force Weapon ID power is a psychic power).

Blessing of the blood god only specifies him, not the unit he is with; so if he is attached to a unit you are free to target that unit with any Psychic power you wish, your opponent(the Kharne player) cannot allocate PSA wounds, nor hits, and Kharne would be immune to the effects of a psyker battle squad(meaning his unit would take the negative to Ld but then Kharne would lend his full Ld 10, but I cannot figure out any time that would come into play since kharne is also Fearless) or anything similar.

Doom gets screwy as you can target the unit he is with with Doom and still get to re-roll hits, then the Kharne player can allocate some of those wounds to Kharne as normal.

P.S. Veil of tears is ignored by Kharne(per the FAQ), as would similar psychic powers, but his squad could still be out of range after the roll(lets say you have your Squad with Kharne exactly 12" away from a harlequin unit and shoot at them, Kharne does not have to worry about the range test and gets his shot the rest of the unit as a whole takes the Range test and finds that they only have a spot range of 8" and are therefore out of range).

Confusion but sounds fun

Yeah I was surprised to see that their is no mention to joined units in the FAQ even though Veil of tears is specifically mentioned.