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Someone is arguing that you can take a psycannon and make it master crafted on a GK purifier or strike squad and I am arguing that he can't do that since the "sarge" can't even take a psycannon. As far as I know only paladins can get master crafted psycannons.

Am I off base for this? Help me settle this debate mighty dakka!

Only the KotF can MC weapons, and he is NOT a purifier so cannot take a Psycannon.

A GKGM can also MC his psycannon

Yep. Just as I thought. Guess he can have a MC storm bolter if he wanted it kekekeke.

Wierdly enough though, could you potentially master craft empyrean Brain Mines and orbital bombardment?

Master crafted OB let's you re-roll scatter and you cant master craft grenades IIRC