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Sculpey is oven-hardening clay. Long science short, it "dries" by removing moisture from the clay and thus hardening. However, because you're removing something, the stuff will shrink slightly but noticeably. This reason alone makes it unfit for sculpting fine miniatures.
"Green Stuff" is an Epoxy Putty. You mix the two parts, and the two-part epoxy chemically reacts and hardens over time. Because nothing is really being 'removed', there is no shrinkage.
Additionally, "Green Stuff" is workable until it fully hardens. You can sculpt the general shape, let it harden a bit, then continue sculpting when it is at medium hardness.
Finally, you can add on bits to existing, hardened things you've sculpted. Sculpey requires you to re-oven everything.
There is almost no reason to use Sculpey when Green Stuff and other epoxy putties are so much better for your purposes.
Sculpey may be a nice and cheap way to make large things such as Tanks and such maybe.
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