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troll?

Intellect doesnt exist in 40k, if your talking about initiative thats who goes first in close combat.

Weapon skill is also close combat.

To cast a psychic power, No its not a spell, Harry potter casts spells, in 40k we use psychic powers.

You declare the power in the phase that its used in, and roll a leadership test. If its a shooting attack you roll to hit based on balistic skill.

Lets say my Farseer wants to cast guide on a squad of eldar models. During my Pre Turn when Eldar powers are cast, I select to use guide. I toll two dice, and if they are below 9 the powers go off. Simple as that.