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Best way I've done natural orange:
mid: bubonic brown and blood angels red, probably about 2:1
shade: bestial brown with just a touch of blood red
start with the shade, slowly add in the midtone, if that isn't bright enough, start adding bleached bone
there are other ways to do this, but the key is keeping a moderate amount of brown in it. scorched brown will get a similar, cooler effect
(sorry for the outdated color names, haven't bothered to learn GW's new names)
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