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You don't necessarily need to highlight black if you varnishing it with gloss, it's a quick and easy way of getting a good finish especially if you've got a lot of mins to paint up. Only problem is that with a predominantly black figure a lot of the detail will be lost as the gloss just reflects where the actual light in the environment is coming from rather than where you want to suggest it's coming from with your highlighting. So your Guardians will tend to look a bit 'flat' on the table as the gloss won't necessarily pick out the details of their armour plates for example.
Easiest thing to do IMO is paint them black, put the gloss coat on and see what you think; if they do look a bit flat, give them a highlight on top of the gloss, you can paint over it easily as long as you keep the coat of varnish thin. As for colours, I use GW Codex grey then Fortress grey for the extreme highlight (sorry not sure of the current equivalents).
As far as vehicles go, I think the gloss effect works best on large flat areas with little detail, so should be good for your falcons and wave serpents. Give it a go, if you don't like it you can spray over it easily. Hope that helps.
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