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I will start of:

Adeptus Mechanicus Special Ammunition- are available to sternguard veterans, but only if you have a master of the forge in your army

Firestorm Bolt Rounds, 28 S5 AP4 Assault 3, Soulfire
Electro-Arc Bolt Rounds, 24 S4 AP2 Rapid Fire, Tesla, Haywire
Gorefire Heavy Bolt Rounds, 48 S6 AP5, Heavy 3, Hemo-Reactive (if a model suffers a unsaved wound from this weapon, place a S6 AP3, Poisoned (+3) small blast marker centered on that model)

More Ad-mech Wargear coming up, feel free to submit you own in the meantime.

Electoo (Electric Priest wargear)

Provides a 6++ invulnerable save and can emit lightning strikes with the following profile;

RNG - S5 AP6 Melee, Rending, Tesla