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At the mo I use a brush similar to that of a standard citadel brush but I struggle to get a clean highlight using the edge of the brush, also when i do apply highlights they dry darker than the actual colour so would I need to apply another coat of highlights. (only started highlighting models after having painted them without for while). Any suggestions on what type of brushes to use to get a nice fine clean highlight? And any others tips that could help improve the quality of them. Much thanks to anyone who replies.

Read these, they will probably help:

http://fromthewarp.blogspot.com/2011/08/basics-line-highlighting-made-simple.html
http://fromthewarp.blogspot.com/2011/08/basics-line-highlighting-optional.html

I use a detail brush from games workshop to get my highlights.
I get a lot of people saying they look like they are out of tron, but im happy with the result. Take a look.