So after much thinking I've decided that I'd like to go with an autumnal colour scheme with my High Elf army. A mixture of rich browns, golds, bronze and reds for the general army - with then being able to pick out things like silver helms with a shot of white/silver as well.
Partly inspired by the elves from Disciples and their colour scheme:
http://images.eurogamer.net/assets/articles/a/6/3/9/3/4/ss_preview_disciples3_elves.jpg
http://angryclownent.com/wp-content/uploads/2010/07/Disciples-3-1683.jpg
http://s.cghub.com/files/Image/107001-108000/107028/958_max.jpg
Though with a touch more richness (like the last link shows ) so that its not too monotone on the table top.
Thing is I'm an utter beginner with paints so I've no idea really how to devise nor get the right colours on the models themselves. If anyone has done a similar scheme or knows of any I'd welcome a look at them to get an idea of how people have approached it. I'd also greatly welcome advice on paints and what colours to select and layer so that I can get a good effect.