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Slaanesh, or if the gods aren't directly in the movie, a greater daemon of Slaanesh: David Bowie, with the voice of Lady GaGa over his when he/she speaks. Justin Bieber also might make a good Daemonette.

Khorne: Terry Crews

Papa Nurgle: Morgan Freeman in a pus-riddled fat suit

Tzeentch: Ian McKellen

The Emperor of Mankind: idk, this one is tough. I was thinking the guy who played Thor but he doesn't really suit the eloquent and kind yet commanding voice I imagine the big E to have.