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Is this possible?
I understand that if it walks 6" and then troops disembark, the rules specifically write the Naut/transport can't do any additional movement, including charges.
But what if the Naut moves after they disembark? It can charges?

Does the 'naught have the Assault Vehicle special rule? If not, you cannot charge after disembarking, regardless of what the vehicle does.

I think he's asking if the 'naught can assault, not the disembarking troops.

Ah true. Then yes, the rules clearly state that if the vehicle does not move first, then it can move normally that turn. Normal movement includes charging.