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I'm trying to come up with decent Dark Eldar TAC lists and I'm tempted to throw archangel of pain on a succubus or archon with a webway portal.

In a Raider this would have a pretty large area of effect and could get a few enemy squads when used with the webway portal

I could see this causing chaos with armies like gun line guard and Tau but i'm wondering whether its worth it because against space marines its a waste of 25 points.

TAC lists are still very meta specific. What is your meta made up of? If everyone plays a SM variant then it might not be worth it.

Its mostly Eldar. I think there's only one dedicated marine player and a couple space wolf players.

Do you think it'd be worth it if I'm not fighting marines much?