I'm a newcomer to airbrushing as well, and have run into most of what you have.
Your first mistake was to paint on a model first. Spray onto some paper, newspaper, card stock, anything other than those expensive minis

Get a real feel for how the brush works before touching a model. If you can't make a piece of paper a uniform grey by spraying black at it, you probably aren't ready to prime a model with an airbrush.
Is your Master brush a dual action? Gravity fed is nice, but it's the dual action that's the first key to success. Dual action allows you to feather the amount of paint coming out of the tip.
Thinning the paints is pretty much a necessity. Even using Vellejo Model Air, I thin them down a bit. Just how thin you have to go depends mostly on the needle size you're using, and the effect you're going for. Mine is a .35mm.
The black wash effect you got was from thinning too much. The dry tip (air coming out, but no paint) is from not thinning enough. With
GW paints, I'd start with roughly 50/50 paint/thinner (I use Vellejo paint thinner - works great, but distilled water is good too). This ratio is not set in stone, especially with
GW paints. Their decision to NOT use dropper bottles is a serious facedesk.
Blowing metals through the airbrush is tricky.
GW paints have rather large flecks of metal in them, so if you're using a small needle, it's gonna clog up FAST.
So all that said: I'll boil it down a bit:
Step 1: Start with Chaos Black. Thin 50/50 with your fluid of choice
Step 2: Practice on a piece of white paper
Step 3: Adjust thinning ratio and observe effects
Step 4: Clean the brush regularly while using
Repeat step 2 LOTS. Airbrushing is not nearly as easy as the youtubers make it look. As for step 4, I keep a Q-tip soaking in a little airbrush cleaner. Use the Q-tip (cotton swab, w/e) to GENTLY clean the needle tip while using. If you can see any dried paint on the tip, stop what you're doing and clean it off. Adjust your thinning ratio if you got less than 30 seconds of spray time.
Hope this helps a bit.