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If a psycher uses Spontaneous Combustion to target a model with "look out sir" ability, If that model passes the look out sir roll and a jobber in the unit dies, does the second part of the spell trigger (meaning the template) ?

The actual target of the spell didnt die.

I would think yes, at least RAI.

I'd just look at it as the target of the spell changing. LOS means that instead of hitting the character you're hitting a grunt, and if you hit and kill said grunt he'll explode.