1. Marines don't have to be blue. There are 1000 (ish) 'Chapters' which all have their own colour scheme. But there's nothing wrong doing Ultramarines if you like their scheme. GW are now stocking Macragge Blue spray. Use a spray primer, either grey or black (I use Halford's) then use the Macragge Blue spray.
2. There are many companies out there which do stuff. Warlord Games also do coloured sprays & so do B&Q. WG & GW do paint stations which are handy but not essential. One thing you do need is a decent light source. Look on Amazon for a hobby lamp with a daylight bulb. Also buy decent brushes - ie not a cheap set from the Works. Use a white bathroom tile (cheap) on which to water down & mix your paints on or buy an artist's palette (more expensive).
3.Once you have a blue marine, I would use a blue wash (eg GW's Drankenhof Nightshade). If using Vallejo, mix a dark blue with their glaze medium & water. Coat the mini with this. It will settle in the cracks & crevices & shade the model. Once this is dry, use a lighter blue to add highlights on the raised parts of the model. Pick out details like the eyes, the chest eagle, purity seals etc. It might be easier to shade these with black first.
4. I find that some red will help any model pop.
5. I base my models mostly with sand mixed with railway modelling ballast. Glue this onto the base with watered down PVA.
6. Check out these pages & search youtube for videos for more help.
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