I don't use hairspray but I do use Mig Productions Chipping Fluid, which works the same way (it just doesn't smell).
I always let my base coat dry at least overnight, if not longer. As soon as the chipping fluid is dry to the tough, I spray the next layer of paint on it and as soon as that is dry to touch, I start chipping. I've found that the longer I waited, the harder it was.
Also, what brand of paint are you using?
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