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So let's say you give a Moritat a pair of volkites and put him in an alpha legion group or blackshields group. He now re rolls 1's when shooting giving him a 1/36 chance to "miss" thus ending chain fire. Am I missing something or does he basically get 72+ shots every other turn?

how are you getting the re-roll?

The faq states this:
Replace the ‘Lone Killer’ rule with the following:
 Lone Killer – A Moritat may not be taken as a Compulsory HQ choice, only as an optional
HQ choice, and may never be the army’s Warlord. Note that this means a Moritat may not be
taken as part of an Allied Contingent. They may not join units or travel inside transports with
other units except Legion Destroyer squads. They may not benefit from any Blessing type
psychic powers, or from Leadership bonuses, Leadership re-rolls or other beneficial special
rules provided by other friendly models or army-wide effects which are the result of a Rite of
War.

That would be what I was missing: the Faq. Thanks.

{Edit} never mind, too early for reading comprehension apparently {/Edit}