Just theorizing/shooting from the hip here... but could it be that Prime is "optimized" for the PS4 OS, and doesn't quite like the PS3? I know I have issues on my PS3 that are similar to yours, that I do not have on the PS4.
I do know that one thing that will cause it to change picture quality is buffering issues, which as I said, could be down to software issues beyond your control, or it could be due to the bandwidth getting used someplace else.
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