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I've read about characters becoming daemons and daemon princes of Chaos Undivided. How would one represent this modelwise?

For game purposes, I think all daemons/daemon princes have to be a "Daemon of _____"...aside from Be'lakor, I think...

A daemon prince would be the best thing to do as an undivided daemon though, as it can be a daemon of any god, it's not associated with one by default, as most other daemons are.

The easiest way to go about it would probably just be to give it a colour scheme that doesn't particularly point to any god, so avoid red, blue, green, and pink/purple...or combine all those colours somehow?

While DPs haven't always had to be aligned, the current fluff does require it. After all, 1 of the 4 Chaos gods has to bless the mortal with power for them to turn into a DP.

I feel like Chaos "Undivided" is a misnomer. It should really be Chaos "United" as the only way to do it is to have units from all 4 alignments present in your army.

Belakor, however, is the only Daemon blessed with the power of multiple gods and is probably the best reference for a color scheme. He should also be your default HQ because of this.

Aren't there daemon primarchs of Chaos Undivided?

 Matthew wrote:
Aren't there daemon primarchs of Chaos Undivided?

I believe Perturabo and Lorgar are Undivided daemon primarchs.

It is actually possible to have an undedicated daemon prince. As far as I am aware, it can only be achieved in game by an unmarked character achieving diabolic splendour.

I guess undivided daemon princes are so rare that we can only play their 'origin story' on the table.

 Matthew wrote:
Aren't there daemon primarchs of Chaos Undivided?

Probably. I don't think the details of the 'undivided' primarchs' ascensions ever got described. We don't know. We do know they aren't all entirely secular. Peturabo has dabbled in Nurgle Daemonic Sorcery, as an example.