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Perhaps look up some tutorials for Dark Eldar armour, quite often you'll see them done in grey/black with extreme highlights suggesting colour and the same theory could be applied here.
Alternatively, what you're suggesting would work, though I'd possibly look up mixing a wash that's more bluey-green/sea green as Waywatcher is a really strong straight green. But the theory is sound, start from black, highlight up to a light grey, glaze (rather than wash) the whole thing in a dark green to give it a bit of a tint. You might need two or three coats for the glaze to really work.
Giving the armour a thin coat of gloss varnish (Avoiding any other areas) might also aid in that shiny and smooth effect, though it might make photographing the model a bit of a pain.
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