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Looks like the base is Leadbelcher.
The red appears to have some reflective qualities so I would hazard a guess that's Spiritstone over the Leadbelcher, then hit with Carroburg Crimson to darken it a little and mute the reflection.
The brown appears again metallic, I'd probably hazard it started with Warplock Bronze and then Runelord Brass.
The scythes appear to have the typical paint style you see on a lot of power weapons, the upper highlight's a bright orange of one form or another. I'm not sure how dark you should start, either.
Hope that helps some.
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