You can look these things up pretty good on the net but here is something quick:
 The easiest way to figure out the angles of a symetrical shape is: 360 degrees divided by the number of sides and subtract the result from 180 degrees (corner angle = 180-(360/N)
 
 Equilateral Triangle = 60 deg
 Pentagon (5 sides) = 108 deg 
 Hexagon (6 sides) = 120 deg
 Octogon (8 sides) = 135 deg
 Decagon (10 sides) = 144 deg
 
 You can then imagine how you would like your bunker to look if you take any of these shapes and flatten them out by cutting a section off from corner to corner.
 A "Quonset hut" for instance would look good if you cut a Decagon in half.
 A solid looking bunker would look good as an Octagon with the bottom 3 sides removed (vertical sides, 135 deg slopes, flat roof)
 
 Hope that helps.  I never gave that much thought before so it was a good exercise! 
 
  
 
 Ah, you posted more while I wrote this.
 
 The bunker you show there, ah a "compound miter".
 This calculator should work for you:
 
https://www.blocklayer.com/compoundmitereng.aspx
 
 Assume the sloped walls on the bunker are 1/4" thick.
 It looks like it is an Octagon so sides = 8
 I would hazard a guess the slope is = 60 deg.
 
 Play with it a bit and it starts making sense, the other long method involves "tan" ... I can explain further if needed but this tool "should" work.