Back in the day I painted a whole necron army using an airbrush with Humbrolls enamel paints, namely a cobalt blue metal and the brightest possible silver I could find (the customer wanted me to replicate the look of terminator in the t2 movie poster)
I would say that overall enamel-based metallics look better than acrylics on large surfaces, if aplied flat.
Here is a pic with some destroyers from that army to show you what I mean