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No, it wouldn't.
You'd need to 'clad' the styro in something to get any decent glue to allow a good bond between the styrofoam and plastic.
Cardboard can be glued to the styrofoam with pva - when you let it dry properly it will stay there. When it is dry, you can use polycement (regular model glue) to glue plastic to cardboard (it can take a while, but it WILL work). Superglue will also work with this method.
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