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It's going to depend on what kind of quality you want and what you want to spend. I quite like GW's Chaos Black spray primer. It's got a good tooth to it (the quality that makes it retract a bit, thereby clarifying edges, corners, etc.).
Krylon is another popular one. I've used their black spray primer, and it's decent. It's not quite as dark (GW's is pretty much jet black), and it's more of a matte (GW's is pretty glossy). It doesn't have quite as much tooth as GW's, but the can I have has about 25% more primer and cost about 1/3 of what GWs cost.
I've heard lots of good things about Gesso and Vallejo, but, if I understand correctly, they're both exclusively brush-on primer, and, milliliter-for-milliliter, more expensive than GW's spray primer. Of course, with brush on, you're not going to lose much, if any, where a decent amount of your spray primer will be lost to whatever your model is on as you spray.
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