I have done some costum marine legs from time to time. My older ones are
GS, i made some with pure Milliput and my newest are made in a milliput-
GS mix. What i find very heplfull is to use a hard cureing putty that can be filed and sanded like milliput or milliput-
GS mix.
Those are the steps i do.
1) Armature from a sturdy wire bent into pose and wrapped with Milliput as a basic surface for sculpting.
2) Add the crotch armor
3) sculpt the upper legs and file/sand them smooth
4) Build the lower leg either as a piece going over the knees of leave room for a knee pad.
5) glue small plasticard pieces onto the wire in the rough shape of the whole feet as the ground of the feet. Just make them a little bit smaller than the actuall feet to leave sculpting room.
6) file/sand the lower legs and correct the lower edge of the armor to get them even and looking good next to normal legs
7) sculpt the actuall feet onto the plasticard.
8) add kneepad if needed and additionla details.
If you are comfortable with sculpting you can press in additional details in steps 2, 3 and 4 like the space marine legs have.
Here are some examples of legs i created using those steps.