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"Priming" is a bit of a fuzzy term, as the verb "to prime" is frequently used in a general sense (the first coat of paint, usually a single color (black, white, grey) sprayed on), but the noun "primer" refers to a type of paint distinct from the usual enamel sprays (more tooth, better adhesion, etc.).
While I use plain old enamels (Walmart's ColorPlace line has treated me well) on plastic, they just don't cut it on metals. For those, I've had good luck with Krylon's Indoor/Outdoor Primer (I use grey). Given enough time to cure, it's pretty resilient stuff and the color is a nice, neutral light-medium grey (akin to the old Codex Grey).
As far as variety is concerned, every brand will behave slightly differently and color choices vary, but there are a few general types to watch out for. Self-etching primers eat into the surface, slightly, which gives them a very strong hold. They are, however, more caustic and can potentially damage more delicate materials. Sandable primers go on thick to fill minor surface imperfections, leaving a very nice surface for painting... after subsequent fine sanding. The difficulty of doing so with a miniature means that they're just more likely to fill in details. Both types are usable on minis (I've seen them recommended on Dakka, before), but I wouldn't personally choose either over their generic/plastic-safe counterparts.
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