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Hey I'm trying to make a good starting grey knights army at 750 but Idk what to get frist???

I'm not sure you'll get much for that low a points total but you should start with a librarian in terminator armour and a squad of terminators. The cool thing is that you can use the warding stave and arm from the terminator squad on the librarian as the finecast warding stave he comes with tends to bend. After that look at getting a dreadknight. Depending on the kit you give them all of this should get you around the 600 points mark. A good idea after that is to grab a vindicare assassin as he is one of the cheapest options for ignores cover that we can get. Hope this helps

Librarian is 125 to 170 points depending on upgrades
5man Terminators with a psycannon, a hammer and halberds is about 200 points (a little over)

The Nemesis Strike Force detachment only requires 1 Troops choice so the above is enough to start.

From there you can fill out your army. I'd start with Dreadknights and more Terminators. Then maybe a StormRaven for airsupport. Almost every unit is a little over 200 points except the Librarian so at 750 points you can fit 1 Librarian, 1 Terminator units and 2 more units of either Dreadknight, Stormraven, 5 Purifiers in Rhino or 5 Terminators. Those are my go-to units.