Soviet steel case ammo is normally steel lacquered green - you see it especially common in 7.62x39mm ammo.
As to the slug itself, you'll see brass and copper most commonly, but not exclusively - I have an old .303 British round from Dominion Arsenal in '42 that's a very nickel-heavy jacket on a brass case, looks pretty sweet, I can take some pics of these rounds if you want.
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