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For khorne I'm pretty sure it's Anngrath for the thirsters now, and either Doombreed or Angron depending on who you talk you.

And just some food for thought, I'm pretty sure Guilliman defeated Angron pre-daemon, then beat lorgar, then beat the newly formed daemon angron.
Perhaps old Rouboute isn't quite the 'Girlyman" everyone makes him out to be...